HomeIngredient LibraryCitric Acid

Ph Adjuster

Citric Acid

Citric Acid is a ph_adjuster, chelator, antioxidant, preservative_booster, exfoliant used in cosmetic and personal-care formulation. Typical use level is 0.1%–10%. It is water-soluble. Stable in the pH 2–6.5 range.

At a glance

CAS number
77-92-9
INCI name
Citric Acid
Function
ph_adjuster, chelator, antioxidant, preservative_booster, exfoliant
Typical use level
0.1%–10%
Solubility
water
Stable pH
2–6.5

CAS number and synonyms are sourced from PubChem. Function, usage levels, pH and compatibility are AI-assisted formulation guidance — verify against your supplier's technical data sheet and applicable regulations before use.

Also known as

citric acid 2-hydroxypropane-1,2,3-tricarboxylic acid Citric acid, anhydrous Aciletten Anhydrous citric acid Citro Citretten Citric acid anhydrous Chemfill Hydrocerol A 1,2,3-Propanetricarboxylic acid, 2-hydroxy- 2-hydroxy-1,2,3-propanetricarboxylic acid

Compatibility

Works well with:
Niacinamide Hyaluronic Acid Glycerin AHA Acids Sodium Citrate Vitamin C (L-Ascorbic Acid) Kojic Acid Allantoin Panthenol Preservatives (Phenoxyethanol)

Use caution with:
Sodium Bicarbonate Calcium Carbonate Strong Bases (Sodium Hydroxide at high conc.) Oxidizing Agents Retinol (at high conc.)

Citric acid reacts with carbonates and bicarbonates causing effervescence and neutralization, making pH control unpredictable. It can chelate divalent metal ions, which may destabilize formulations relying on calcium or magnesium for structural integrity. At very low pH levels it may accelerate degradation of sensitive actives such as retinol.

Formulation notes

Classified as an AHA at higher concentrations (above ~3%); EU cosmetics regulations require labeling warnings for AHA-containing products above certain thresholds. At low levels (0.1–0.5%) primarily used as a pH adjuster/buffer. Use caution on sensitive or compromised skin at elevated concentrations. Generally recognized as safe (GRAS) by the FDA.

Frequently asked questions

What is Citric Acid?

Citric Acid is a ph_adjuster, chelator, antioxidant, preservative_booster, exfoliant used in cosmetic and personal-care formulation. Typical use level is 0.1%–10%. It is water-soluble. Stable in the pH 2–6.5 range.

What is Citric Acid used for?

Citric Acid is used as ph_adjuster, chelator, antioxidant, preservative_booster, exfoliant in cosmetic and personal-care formulations.

What is the typical use level of Citric Acid?

Citric Acid is typically used at 0.1%–10% in the finished formulation. Always confirm against your supplier's technical data sheet.

What is the CAS number of Citric Acid?

The CAS registry number for Citric Acid is 77-92-9. Its INCI name is Citric Acid.

At what pH is Citric Acid stable?

Citric Acid is generally stable in the pH 2–6.5 range.

What ingredients are compatible with Citric Acid?

Citric Acid works well with Niacinamide, Hyaluronic Acid, Glycerin, AHA Acids, Sodium Citrate, Vitamin C (L-Ascorbic Acid), Kojic Acid, Allantoin, Panthenol, Preservatives (Phenoxyethanol). Use caution when combining it with Sodium Bicarbonate, Calcium Carbonate, Strong Bases (Sodium Hydroxide at high conc.), Oxidizing Agents, Retinol (at high conc.).

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